QIU Kun,XU Suo-cheng,TIAN Hua,ZHENG Xi,LV Tian-shuai,LU Qi-fei,WANG Da-jian.Composition-induced valence variation of europium and the photoluminescence properties for Eu2+ doped borophosphate luminous glass in air[J].Optoelectronics Letters,2011,7(5):350-353
Composition-induced valence variation of europium and the photoluminescence properties for Eu2+ doped borophosphate luminous glass in air
Author NameAffiliation
QIU Kun School of Materials Science & Engineering,Tianjin University of Technology 
XU Suo-cheng School of Materials Science & Engineering,Tianjin University of Technology 
TIAN Hua Key Lab. on Display Materials & Photoelectric Devices Ministry of Education of China,Tianjin University of Techndogy 
ZHENG Xi Key Lab. on Display Materials & Photoelectric Devices Ministry of Education of China,Tianjin University of Techndogy 
LV Tian-shuai Key Lab. on Display Materials & Photoelectric Devices Ministry of Education of China,Tianjin University of Techndogy 
LU Qi-fei Tianjin Key Lab. for Photoelectronic Materials & Devices, Tianjin University of Technology 
WANG Da-jian School of Materials Science & Engineering,Tianjin University of Technology Key Lab. on Display Materials & Photoelectric Devices Ministry of Education of China,Tianjin University of Techndogy Tianjin Key Lab. for Photoelectronic Materials & Devices, Tianjin University of Technology 
Abstract:
      A simultaneous blue-light and red-light emitting glass of SrO-B2O3-P2O5 doped with Eu2O3 is prepared in air, and then heat-treated without any reductive reagent. A transition combination is found to consist of a band emission peaked around 430 nm and a series of line emission from 593 nm to 611 nm, corresponding to the typical 4f65d→ 4f7 transition of Eu2+ and 5D0 → 7FJ (J = 0, 1, 2, 3, 4) transitions of Eu3+, respectively. Some unidentified crystals such as Sr (PO3)2 and SrB2O4 as hosts for Eu2...
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