QIU Kun,XU Suo-cheng,TIAN Hua,ZHENG Xi,LV Tian-shuai,LU Qi-fei,WANG Da-jian.Composition-induced valence variation of europium and the photoluminescence properties for Eu2+ doped borophosphate luminous glass in air[J].Optoelectronics Letters,2011,7(5):350-353 |
Composition-induced valence variation of europium and the photoluminescence properties for Eu2+ doped borophosphate luminous glass in air |
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Abstract: |
A simultaneous blue-light and red-light emitting glass of SrO-B2O3-P2O5 doped with Eu2O3 is prepared in air, and then heat-treated without any reductive reagent. A transition combination is found to consist of a band emission peaked around 430 nm and a series of line emission from 593 nm to 611 nm, corresponding to the typical 4f65d→ 4f7 transition of Eu2+ and 5D0 → 7FJ (J = 0, 1, 2, 3, 4) transitions of Eu3+, respectively. Some unidentified crystals such as Sr (PO3)2 and SrB2O4 as hosts for Eu2... |
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