Deng Zhen-bo,Chen Zheng,Wu Hui,Lü Zhao-yue,Du Hai-liang,Zou Ye,Zhang Guo-liang,Zhou Mao-yang.High efficiency bulk heterojunction organic solar cell by using high conductivity modified PEDOT: PSS as a buffer layer[J].Optoelectronics Letters,2012,8(5):336-339
High efficiency bulk heterojunction organic solar cell by using high conductivity modified PEDOT: PSS as a buffer layer
Author NameAffiliation
Deng Zhen-bo Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, China 
Chen Zheng Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, China 
Wu Hui Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, China 
Lü Zhao-yue Department of Physics, School of Science, East China University of Science & Technology, Shanghai 200237, China 
Du Hai-liang Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, China 
Zou Ye Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, China 
Zhang Guo-liang Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, China 
Zhou Mao-yang Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, China 
Abstract:
      In this paper, bulk heterojunction solar cells with poly-(3-hexylthiophene) (P3HT): [6,6]-phenyl-C61-butyric-acid-methylester (PCBM) as an active layer and modified poly (3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) as a buffer layer are fabricated. The buffer layer is modified by adding 1% to 5% dimethyl sulfoxide (DMSO) into PEDOT: PSS solution before spin-coating. The conductivity of modified PEDOT:PSS and the performance of solar cells with modified PEDOT:PSS are measured. The highest conductivity of modified PEDOT:PSS with 4% DMSO can achieve 89.693 S/cm. The performance of organic solar cell with PEDOT:PSS modified by 4% DMSO is the best. The 4% DMSO-modified-PEDOT:PSS cell has a power conversion efficiency of 3.34%, V oc of 5.7 V, J sc of 14.56 mA/cm2 and filling factor (FF) of 40.34%.
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This work has been supported by the National Natural Science Foundation of China (Nos.60977027 and 60825407), the Fundamental Research Funds for the Central Universities (No.2010JBZ003), and the Beijing Municipal Science & Technology Commission (No.Z090803044009001).
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