Bao-long Xu,Chang-xin Liu,Hai-yan Sun,Yu-rong Zhong.Fabrication and photo-catalytic properties of pure and cation doped TiO2 nanotube arrays[J].Optoelectronics Letters,2014,10(2):84-87 |
Fabrication and photo-catalytic properties of pure and cation doped TiO2 nanotube arrays |
Author Name | Affiliation | E-mail | Bao-long Xu | School of Opto-Electronic Information Science and Technology, Yantai University, Yantai, 264005, China | xubl9796@sina.com | Chang-xin Liu | School of Opto-Electronic Information Science and Technology, Yantai University, Yantai, 264005, China | | Hai-yan Sun | School of Environmental and Materials Engineering, Yantai University, Yantai, 264005, China | | Yu-rong Zhong | School of Opto-Electronic Information Science and Technology, Yantai University, Yantai, 264005, China | |
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Abstract: |
The highly ordered and vertically oriented pure TiO2 nanotube arrays (TONTAs) are synthesized by anodic oxidation of titanium foils in fluoride-based electrolytes under different temperatures and voltages. Then TONTAs are treated at different temperatures. X-ray diffraction (XRD) patterns show that its structure is anatase at 500 °C with the temperature increasing to 700 °C, the most of anatase will transform to rutile, the nanotube arrays form granular titanium oxide, while at 900 °C, anatase will transform to rutile completely. The experimental results of photocatalytic degradation of methylene blue solution show that the cobalt-manganese co-doped TONTAs have good photocatalytic degradation efficiency. |
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This work has been supported by the National Natural Science Foundation of China (No. 11105117), Province Natural Science Foundation of Shandong (No.Y2004A 11) and Yantai University Postdoctoral Foundation (No.WL03B 15). |
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