Jun Song,Liang Sun,Jian Li,Jian Ma,Da-jian Wang.Luminescence properties of a solid solution typed (Ba,Ca)3MgSi2O8: Eu2+, Mn2+ phosphor with a 660 nmfeatured photosynthetic action spectrum[J].Optoelectronics Letters,2014,10(5):343-346 |
Luminescence properties of a solid solution typed (Ba,Ca)3MgSi2O8: Eu2+, Mn2+ phosphor with a 660 nmfeatured photosynthetic action spectrum |
Author Name | Affiliation | E-mail | Jun Song | Institute of Materials Physics, Tianjin University of Technology, Tianjin, 300384, China | | Liang Sun | Tianjin Key Laboratory for Photoelectronic Materials and Devices, Tianjin University of Technology, Tianjin, 300384, China | | Jian Li | Institute of Materials Physics, Tianjin University of Technology, Tianjin, 300384, China | | Jian Ma | Tianjin Key Laboratory for Photoelectronic Materials and Devices, Tianjin University of Technology, Tianjin, 300384, China | | Da-jian Wang | Institute of Materials Physics, Tianjin University of Technology, Tianjin, 300384, China
Tianjin Key Laboratory for Photoelectronic Materials and Devices, Tianjin University of Technology, Tianjin, 300384, China
Key Laboratory of Display Materials and Photoelectronic Devices, Ministry of Education, Tianjin University of Technology, Tianjin, 300384, China | djwang@tjut.edu.cn |
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Abstract: |
A solid-solution-phase Ba1.75Ca1.25MgSi2O8: Eu2+, Mn2+ phosphor in the photosynthetic action spectrum with dual band emissions at 438 nm and 660 nm is fabricated. X-ray diffraction (XRD) confirms the presence of the solid-solution phase. With the supporting information from the diffuse reflection spectrum, a feasible way to obtain higher energy-transfer (ET) efficiency is attained, and the ET efficiency of Eu2+-Mn2+ is enhanced to 76%. The mechanism of this enhancement is owing to variation of the solid solution composition of Ca3MgSi2O8 and Ba3MgSi2O8, which contributes to the extension of the critical distance. Temperature-dependent results show an enhancement which is attributed to Ca. These enhancements show great promise for improving eco-lighting devices. |
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This work has been supported by the National Natural Science Foundation of China (No.21076161). |
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