YOU Jian-qi,LU Wei,QI Shuai,LI Ya-min,SHI Xian,TIAN Zhi,WANG Zhi-jun,ZHANG Kun,PANG Li-bin.Improving the luminescence properties of Ba3Eu(PO4)3 by doping Sm3+ as sensitizer[J].Optoelectronics Letters,2015,11(6):430-433
Improving the luminescence properties of Ba3Eu(PO4)3 by doping Sm3+ as sensitizer
Author NameAffiliation
YOU Jian-qi College of Physics Science & Technology, Hebei University, Baoding 071002, China 
LU Wei Tangshan Vocational & Technical College, Tangshan 063000, China 
QI Shuai College of Physics Science & Technology, Hebei University, Baoding 071002, China 
LI Ya-min College of Physics Science & Technology, Hebei University, Baoding 071002, China 
SHI Xian College of Physics Science & Technology, Hebei University, Baoding 071002, China 
TIAN Zhi College of Physics Science & Technology, Hebei University, Baoding 071002, China 
WANG Zhi-jun College of Physics Science & Technology, Hebei University, Baoding 071002, China 
ZHANG Kun Industrial & Commercial College, Hebei University, Baoding 071002, China 
PANG Li-bin College of Physics Science & Technology, Hebei University, Baoding 071002, China
Department of Foreign Language Teaching and Research, Hebei University, Baoding 071002, China 
Abstract:
      For enhancing the emission intensity and broadening the excitation region of Ba3Eu(PO4)3 (BEP), Sm3+ is doped as sensitizer in this paper. BEP:Sm3+ can produce an obvious red emission at near ultraviolet (n-UV) radiation. An effective energy transfer from Sm3+ to Eu3+ is proved. The commission international de I’Eclairage (CIE) chromaticity coordinates of BEP:Sm3+ locate at red region. When the environment temperature is 150 °C, the emission intensity of BEP:0.10Sm3+ is decreased to 76% of the initial one at room temperature, and the activation energy is calculated to be 0.164 eV, which can prove the good thermal stability of BEP:Sm3+. The results indicate that BEP:Sm3+ may have potential applications in white light emitting diodes (LEDs).
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This work has been supported by the National Natural Science Foundation of China (No.50902042), the Natural Science Foundation of Hebei
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