YOU Jian-qi,LU Wei,QI Shuai,LI Ya-min,SHI Xian,TIAN Zhi,WANG Zhi-jun,ZHANG Kun,PANG Li-bin.Improving the luminescence properties of Ba3Eu(PO4)3 by doping Sm3+ as sensitizer[J].Optoelectronics Letters,2015,11(6):430-433 |
Improving the luminescence properties of Ba3Eu(PO4)3 by doping Sm3+ as sensitizer |
Author Name | Affiliation | YOU Jian-qi | College of Physics Science & Technology, Hebei University, Baoding 071002, China | LU Wei | Tangshan Vocational & Technical College, Tangshan 063000, China | QI Shuai | College of Physics Science & Technology, Hebei University, Baoding 071002, China | LI Ya-min | College of Physics Science & Technology, Hebei University, Baoding 071002, China | SHI Xian | College of Physics Science & Technology, Hebei University, Baoding 071002, China | TIAN Zhi | College of Physics Science & Technology, Hebei University, Baoding 071002, China | WANG Zhi-jun | College of Physics Science & Technology, Hebei University, Baoding 071002, China | ZHANG Kun | Industrial & Commercial College, Hebei University, Baoding 071002, China | PANG Li-bin | College of Physics Science & Technology, Hebei University, Baoding 071002, China Department of Foreign Language Teaching and Research, Hebei University, Baoding 071002, China |
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Abstract: |
For enhancing the emission intensity and broadening the excitation region of Ba3Eu(PO4)3 (BEP), Sm3+ is doped as sensitizer in this paper. BEP:Sm3+ can produce an obvious red emission at near ultraviolet (n-UV) radiation. An effective energy transfer from Sm3+ to Eu3+ is proved. The commission international de I’Eclairage (CIE) chromaticity coordinates of BEP:Sm3+ locate at red region. When the environment temperature is 150 °C, the emission intensity of BEP:0.10Sm3+ is decreased to 76% of the initial one at room temperature, and the activation energy is calculated to be 0.164 eV, which can prove the good thermal stability of BEP:Sm3+. The results indicate that BEP:Sm3+ may have potential applications in white light emitting diodes (LEDs). |
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This work has been supported by the National Natural Science Foundation of China (No.50902042), the Natural Science Foundation of Hebei |
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