ZHENG Xuan,MING An-jie,YE Li,CHEN Feng-hua,SUN Xi-long,LIU Wei-bing,LI Chao-bo,OU Wen,WANG Wei-bing,CHEN Da-peng.Formaldehyde gas sensor based on TiO2 thin membrane integrated with nano silicon structure[J].Optoelectronics Letters,2016,12(4):308-311
Formaldehyde gas sensor based on TiO2 thin membrane integrated with nano silicon structure
Author NameAffiliation
ZHENG Xuan School of Electronic, Electrical and Communication Engineering, University of Chinese Academy of Sciences, Beijing 100049, China 
MING An-jie Smart Sensing Research and Development Centre, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China 
YE Li Laboratory of Advanced Polymer Materials, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China 
CHEN Feng-hua Laboratory of Advanced Polymer Materials, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China 
SUN Xi-long School of Electronic, Electrical and Communication Engineering, University of Chinese Academy of Sciences, Beijing 100049, China 
LIU Wei-bing Smart Sensing Research and Development Centre, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China 
LI Chao-bo Smart Sensing Research and Development Centre, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China 
OU Wen Smart Sensing Research and Development Centre, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China 
WANG Wei-bing Smart Sensing Research and Development Centre, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China 
CHEN Da-peng Smart Sensing Research and Development Centre, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China 
Abstract:
      An innovative formaldehyde gas sensor based on thin membrane type metal oxide of TiO2 layer was designed and fabricated. This sensor under ultraviolet (UV) light emitting diode (LED) illumination exhibits a higher response to formaldehyde than that without UV illumination at low temperature. The sensitivities of the sensor under steady working condition were calculated for different gas concentrations. The sensitivity to formaldehyde of 7.14 mg/m3 is about 15.91 under UV illumination with response time of 580 s and recovery time of 500 s. The device was fabricated through micro-electro-mechanical system (MEMS) processing technology. First, plasma immersion ion implantation (PIII) was adopted to form black polysilicon, then a nanoscale TiO2 membrane with thickness of 53 nm was deposited by DC reactive magnetron sputtering to obtain the sensing layer. By such fabrication approaches, the nanoscale polysilicon presents continuous rough surface with thickness of 50 nm, which could improve the porosity of the sensing membrane. The fabrication process can be mass-produced for the MEMS process compatibility.
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