Yang Xiao-yan,Wu Xiao-ming,Jiang Chun-xia,Han Xue-song,Gao Zhi-qi,Shen Li-ying,Wei Jun,Yin Shou-gen.Research of organic field effect transistors based on semiconducting single-walled carbon nanotubes[J].Optoelectronics Letters,2012,8(4):260-263
Research of organic field effect transistors based on semiconducting single-walled carbon nanotubes
Author NameAffiliation
Yang Xiao-yan Key Laboratory of Display Material and Photoelectric Devices, Ministry of Education of China, Institute of Material Physics, Tianjin University of Technology, Tianjin 300384, China 
Wu Xiao-ming Key Laboratory of Display Material and Photoelectric Devices, Ministry of Education of China, Institute of Material Physics, Tianjin University of Technology, Tianjin 300384, China 
Jiang Chun-xia Key Laboratory of Display Material and Photoelectric Devices, Ministry of Education of China, Institute of Material Physics, Tianjin University of Technology, Tianjin 300384, China 
Han Xue-song Key Laboratory of Display Material and Photoelectric Devices, Ministry of Education of China, Institute of Material Physics, Tianjin University of Technology, Tianjin 300384, China 
Gao Zhi-qi Key Laboratory of Display Material and Photoelectric Devices, Ministry of Education of China, Institute of Material Physics, Tianjin University of Technology, Tianjin 300384, China 
Shen Li-ying Key Laboratory of Display Material and Photoelectric Devices, Ministry of Education of China, Institute of Material Physics, Tianjin University of Technology, Tianjin 300384, China 
Wei Jun Key Laboratory of Display Material and Pho toelectric Devices. Min istry of Education of Ch ina. Institute of Ma terial Physics. Tianjin University of Technology. Tianjin 300384. China Singapore Institute ofManufacturing Technology, 71 Nanyang Drive, Singapore 6380750, Singapore 
Yin Shou-gen Key Laboratory of Display Material and Photoelectric Devices, Ministry of Education of China, Institute of Material Physics, Tianjin University of Technology, Tianjin 300384, China 
Abstract:
      The metal-conducting single-walled carbon nanotubes (m-SWNTs) with small diameters (0.7 nm 1.1 nm) are selectively removed from the single-walled carbon nanotubes (SWNTs) by using HNO3/H2SO4 mixed solution. Semiconducting single-walled carbon nanotubes (s-SWNTs) can be separated efficiently from the SWNTs with high controllability and purity based on this novel method, and the outcome is characterized by Raman spectrum. Moreover, the organic field effect transistors (OFETs) are fabricated based on the poly (3-hexylthiophene-2, 5-diyl) (P3HT), and untreated SWNTs and separated SWNTs (s-SWNTs) are mixed with P3HT, respectively. It could be found that the P3HT/s-SWNT device exhibits a better field effect characteristic compared with the P3HT device. The current on/off ratio is increased by 4 times, the threshold voltage is also increased from ?28 V to ?22 V, and the mobility is increased from 3×10?3 cm2/Vs to 5×10?3cm2/Vs.
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This work has been supported by the National Natural Science Foundation of China (Nos. 60676051, 60876046, 60906022), and the Natural Science Fund of Tianjin (Nos.07JCYBJC12700 and 10JCYBJC01100).
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