| Tian-shuai Lü,Xu-hui Xu,Da-jian Wang,Liang Sun,Jian-bei Qiu.Fabrication,structure and photoluminescence properties of Eu3+-activated red-emitting Ba2Gd2Si4O13 phosphors for solid-state lighting[J].Optoelectronics Letters,2014,10(2):106-110 |
| Fabrication,structure and photoluminescence properties of Eu3+-activated red-emitting Ba2Gd2Si4O13 phosphors for solid-state lighting |
| Author Name | Affiliation | E-mail | | Tian-shuai Lü | College of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, 650093, China | | | Xu-hui Xu | College of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, 650093, China | | | Da-jian Wang | School of Materials Science and Engineering, Tianjin University of Technology, Tianjin, 300384, China | | | Liang Sun | School of Materials Science and Engineering, Tianjin University of Technology, Tianjin, 300384, China | | | Jian-bei Qiu | College of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, 650093, China | qiu@kmust.edu.cn |
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| Abstract: |
| Eu3+-activated red-emitting Ba2Gd2Si4O13 phosphors are prepared via microwave (MW) synthesis and solid-state (SS) method. The structural and luminescent properties of phosphors are investigated by X-ray diffraction (XRD), photoluminescence (PL) spectra and scanning electron microscopy (SEM). Upon 393 nm excitation, compared with the sample sintered by SS method, luminescence enhancement is observed in the sample synthesized by MW method. The mechanism of MW synthesis process is discussed in detail. Results indicate that the PL enhancement is probably related to the concave-convex phosphor surfaces and uniform grains, which may reinforce scattering of excitation light. Our research may further promote the understanding of MW synthesis and extend the application of Eu3+-activated Ba2Gd2Si4O13 in white light-emitting diodes. |
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| This work has been supported by the National Natural Science Foundation of China （Nos.51002068, 51272097 and 61265004）, and the National Natural Science Foundation for Youths ofYunnan （No.2012FD009）. |
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