LI Hong-lian,DI Shuai,LI Wen-duo,Lü Wen-jing,WANG Fan,FANG Li-de.Measurement of CO2 concentration based on supercontinuum laser absorption spectroscopy[J].Optoelectronics Letters,2021,17(3):176-182
Measurement of CO2 concentration based on supercontinuum laser absorption spectroscopy
Author NameAffiliation
LI Hong-lian College of Quality and Technical Supervision, Hebei University, Baoding 071002, China
National and Local Joint Engineering Center of Measuring Instruments and Metrology Systems, Baoding 071002, China 
DI Shuai College of Quality and Technical Supervision, Hebei University, Baoding 071002, China 
LI Wen-duo College of Quality and Technical Supervision, Hebei University, Baoding 071002, China 
Lü Wen-jing College of Quality and Technical Supervision, Hebei University, Baoding 071002, China 
WANG Fan College of Quality and Technical Supervision, Hebei University, Baoding 071002, China 
FANG Li-de College of Quality and Technical Supervision, Hebei University, Baoding 071002, China 
Abstract:
      The concentrations of CO2 were measured by the supercontinuum laser at normal temperature and variable temperature accurately in this paper. The absorption spectra of CO2 at different concentrations (1.2%—9.0%) were measured in the wavelength range of 1 425—1 445 nm under the optical path of 26.4 m at 293 K and 1 atm. The experimental results showed that the positions of the primary and secondary absorption peaks (1 432 nm, 1 437 nm) were consistent with the HITRAN database. A linear model of concentration and signal intensity at 1 432 nm was established. The maximum relative error of the concentration measurement was 3.3%. The line intensities of 99.9% CO2 in the 1 425—1 445 nm at different temperatures (298—373 K, interval of 15 K) were measured. The influence of temperature changes on the concentration measurement result was corrected and the relative error of the concentration measurement was reduced to 1.4%. Finally, the source of the uncertainty of the entire spectrum measurement system was analyzed and evaluated. This paper demonstrate that the supercontinuum laser can achieve the long-distance measurement of the CO2 under normal temperature or variable temperature environment accurately, which provide an important reference for the long-distance gas detection on site and simultaneous detection of multi-component gases.
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